Radiation-induced change of optical property of hydroxypropyl cellulose hydrogel containing methacrylate compounds; As a basis for development of a new type of radiation dosimeter
メタクリル酸エステルを含むヒドロキシプロピルセルロースゲルへの放射線照射に伴う光学特性の変化; 新規ゲル線量計の開発に向けた基礎研究
山下 真一*; 廣木 章博; 田口 光正
Yamashita, Shinichi*; Hiroki, Akihiro; Taguchi, Mitsumasa
It was aimed to develop a novel polymer gel dosimeter to overcome weakness of earlier ones. A cellulose derivative, hydroxypropyl cellulose (HPC), was chosen as a polymer composing gel matrices and processed with a radiation-crosslinking technique in advance to manufacture of a gel dosimeter. Two methacrylate-type monomers, 2-hydroxyethyl methacrylate (HEMA) and poly(ethylene glycol) dimethacrylate (9G), were selected as vinyl-type monomers polymerizing with irradiations. Visual change with irradiation of $$^{60}$$Co $$gamma$$-rays was observed, and haze and UV-vis absorption analyses were conducted to quantify visual changes of irradiated dosimeters. Radiation-induced white turbidity was easily observable directly by our eyes even with $$^{60}$$Co $$gamma$$-irradiation of 1 or 2 Gy. Sensitivity, which was evaluated by haze, toward $$gamma$$-ray dose was dependent on the composition of the vinyl-type monomers. UV-vis spectroscopy indicated that there are at least two different mechanisms leading to white turbidity. It was shown that dose rate effect can be less significant by optimizing composition of the vinyl-type monomers.
使用言語 : English
掲載資料名 : Radiation Physics and Chemistry
: 101
ページ数 : p.53 - 58
発行年月 : 2014/08
出版社名 : Elsevier
特許データ :
論文URL :
キーワード : no keyword
使用施設 :
広報プレスリリース :
受委託・共同研究相手機関 :
登録番号 : AA20140039
抄録集掲載番号 : 42000795
論文投稿番号 : 14423
Accesses  (From Jun. 2, 2014)
- Accesses
分野:Chemistry, Physical
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