Selective cesium removal from radioactive liquid waste by crown ether immobilized new class conjugate adsorbent
クラウンエーテルを保持した新しい複合型吸着剤による放射線汚染水からの選択的セシウム除去
Awual, M. R.; 矢板 毅; 田口 富嗣; 塩飽 秀啓; 鈴木 伸一; 岡本 芳浩
Awual, M. R.; Yaita, Tsuyoshi; Taguchi, Tomitsugu; Shiwaku, Hideaki; Suzuki, Shinichi; Okamoto, Yoshihiro
Conjugate materials can provide chemical functionality, enabling an assembly of the ligand complexation ability to metal ions that are important for applications, such as separation and removal devices. In this study, we developed ligand immobilized conjugate adsorbent for selective cesium (Cs) removal from wastewater. The adsorbent was synthesized by direct immobilization of DB24C8 onto inorganic mesoporous silica. The obtained results revealed that adsorbent had higher selectivity towards Cs even in the presence of a high concentration of Na and K and this is probably due to the Cs-$$pi$$ interaction of the benzene ring. The proposed adsorbent was successfully applied for radioactive Cs removal to be used as the potential candidate in Fukushima nuclear wastewater treatment. The adsorbed Cs was eluted with suitable eluent and simultaneously regenerated into the initial form for the next removal operation after rinsing with water.
使用言語 : English
掲載資料名 : Journal of Hazardous Materials
: 278
:
ページ数 : p.227 - 235
発行年月 : 2014/08
出版社名 : Elsevier
特許データ :
PDF :
論文URL :
キーワード : 福島第一原子力発電所事故; Fukushima Daiichi Nuclear Power Station Accident
使用施設 :
広報プレスリリース :
論文解説記事
(成果普及情報誌)
:
受委託・共同研究相手機関 :
 
登録番号 : AA20140217
抄録集掲載番号 : 42000868
論文投稿番号 : 14525
Accesses  (From Jun. 2, 2014)
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パーセンタイル:0.42
分野:Engineering, Environmental
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