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Dynamic properties of nano-confined water in an ionic liquid

阿部 洋*; 山田 武*; 柴田 薫

Journal of Molecular Liquids, 264, p.54 - 57, 2018/08

Nano-confined water (a water pocket) was spontaneously formed using an ionic liquid (IL), 1-butyl-3-methylimidazolium nitrate ([C$$_{4}$$mim][NO$$_{3}$$]), in [C$$_{4}$$mim][NO$$_{3}$$]-H$$_{2}$$O and [C$$_{4}$$mim][NO$$_{3}$$]-D$$_{2}$$O mixtures. The static average size of the water pocket in [C$$_{4}$$mim][NO$$_{3}$$]-80 mol% D$$_{2}$$O has been estimated to be around 20${AA}$, determined via small-angle neutron scattering measurements. In this study, the dynamics of the water pocket in the IL were directly examined using incoherent quasielastic neutron scattering. Using the H-D difference of a neutron incoherent scattering cross section, the extent of the diffusion of the water molecules in the water pocket was determined. The water pocket could be characterized due to the slow dynamics of the water compared with those of bulk water.


Temperature measurement for in-situ crack monitoring under high-frequency loading

直江 崇; Xiong, Z.*; 二川 正敏

Journal of Nuclear Materials, 506, p.12 - 18, 2018/08



Cavitation damage in double-walled mercury target vessel

直江 崇; 涌井 隆; 木下 秀孝; 粉川 広行; 羽賀 勝洋; 原田 正英; 高田 弘; 二川 正敏

Journal of Nuclear Materials, 506, p.35 - 42, 2018/08



Neutron inelastic scattering study of the $$f$$-electron states in NdPd$$_5$$Al$$_2$$

目時 直人; 山内 宏樹; 鈴木 博之*; 北澤 英明*; 蒲沢 和也*; 池内 和彦*; 梶本 亮一; 中村 充孝; 稲村 泰弘

Journal of the Physical Society of Japan, 87(8), p.084708_1 - 084708_7, 2018/08

$$f$$電子化合物NdPd$$_5$$Al$$_2$$の中性子散乱による研究を行った。0K, 35.4K, 88.3K, 101.5K, and 198.8Kの結晶場レベルを励起スペクトルから明らかにした。$$Gamma_6$$基底状態は主として$$J_z=pm9/2$$の軌道によって構成され、これが大きな負の$$B_{20}=-1.4$$Kと一軸異方性を生じる。結晶場から計算された磁気モーメント, 帯磁率, 磁化曲線, 比熱は実験をよく説明する。CePd$$_5$$Al$$_2$$やPrPd$$_5$$Al$$_2$$と共通した電荷分布の存在は同じ構造を持つアクチノイド化合物においても局在的な性質が重要で、UPd$$_5$$Al$$_2$$の局在5$$f$$電子状態やNpPd$$_5$$Al$$_2$$の重い電子系超伝導にその価数の不安定性が重要な役割をすることを示している。


High stereographic resolution texture and residual stress evaluation using time-of-flight neutron diffraction

徐 平光; Harjo, S.; 小島 真由美*; 鈴木 裕士; 伊藤 崇芳*; Gong, W.; Vogel, S. C.*; 井上 純哉*; 友田 陽*; 相澤 一也; et al.

Journal of Applied Crystallography, 51(3), p.746 - 760, 2018/06

Neutron diffraction texture measurements provide bulk textures with excellent grain statistics even for large grained materials, together with the crystallographic parameters and microstructure information such as phase fractions, coherent crystallite size, root mean square microstrain, macroscopic/intergranular stress/strain. The procedure for high stereographic resolution texture and residual stress evaluation was established at the TAKUMI engineering materials diffractometer. The pole figure evaluation of a limestone standard sample with a trigonal crystal structure suggested that the obtained precision for texture measurement is comparable with the oversea well-established neutron beam lines utilized for texture measurements. A high strength martensite-austenite multilayered steel was employed for further verification of the reliability of simultaneous Rietveld analysis of multiphase textures and macro stress tensors. By using a geometric mean micro-mechanical model, the macro stress tensor analysis with a plane stress assumption showed a RD-TD in-plane compressive stress (about -330 MPa) in martensite layers and a RD-TD in-plane tensile stress (about 320 MPa) in austenite layers. The phase stress partitioning was ascribed to the additive effect of volume expansion during martensite transformation and the linear contraction misfit during water quenching.


High oxide-ion conductivity in Si-deficient La$$_{9.565}$$(Si$$_{5.826}$$[]$$_{0.174}$$)O$$_{26}$$ apatite without interstitial oxygens due to the overbonded channel oxygens

藤井 孝太郎*; 八島 正知*; 日比野 圭祐*; 白岩 大裕*; 福田 功一郎*; 中山 享*; 石沢 伸夫*; 花島 隆泰*; 大原 高志

Journal of Materials Chemistry A, 6(23), p.10835 - 10846, 2018/06

Apatite-type rare earth silicates are attractive materials with exhaust application such as solid-oxide fuel cells, due to its extremely high oxide-ion conductivity below 600$$^{circ}$$C. Interstitial (excess) oxygens have been believed to be responsible for the high conductivity in apatite-type materials. On the contrary, the present study clearly reveals the presence of Si vacancies [] in La-rich La$$_{9.565}$$(Si$$_{5.826}$$[]]$$_{0.174}$$)O$$_{26}$$ instead of the interstitial oxygens, by single-crystal neutron and X-ray diffraction analyses, density measurements and ${{it ab initio}}$ electronic calculations.


Off-gas processing system operations for mercury target vessel replacement at J-PARC

甲斐 哲也; 内田 敏嗣; 木下 秀孝; 関 正和; 大井 元貴; 涌井 隆; 羽賀 勝洋; 春日井 好己; 高田 弘

Journal of Physics; Conference Series, 1021(1), p.012042_1 - 012042_4, 2018/06

At J-PARC an Off-gas processing system has been utilized to a purging process before the target vessel replacement and an air-flow control procedure to minimize radioactivity release during the replacement. In 2011 the first replacement was carried out after a 500 MWh operation, and the tritium release was measured. It was suggested that the tritium release must be less than that measured at the replacement in 2011 even at the nominal operation of 5,000 MWh. Some procedures of an air-flow control and a rubber plug insertion have been introduced from the replacements in 2013, resulting that the amount of tritium release could be reduced to less than that released in 2011 at the nominal operation.


Status report of the chopper spectrometer 4SEASONS

梶本 亮一; 中村 充孝; 稲村 泰弘; 蒲沢 和也*; 池内 和彦*; 飯田 一樹*; 石角 元志*; 村井 直樹; 吉良 弘*; 中谷 健; et al.

Journal of Physics; Conference Series, 1021(1), p.012030_1 - 012030_6, 2018/06

4SEASONS is a medium-resolution thermal neutron chopper spectrometer in the Materials and Life Science Experimental Facility (MLF) at J-PARC. Although 4SEASONS is routinely used for many experiments by internal and external users, upgrading and maintenance work is still underway. This paper reviews the recent improvements of the instrument.


Recovery of helium refrigerator performance for cryogenic hydrogen system at J-PARC MLF

麻生 智一; 勅使河原 誠; 長谷川 勝一; 武藤 秀生; 青柳 克弘; 野村 一隆; 高田 弘

Journal of Physics; Conference Series, 1021(1), p.012085_1 - 012085_4, 2018/06

At J-PARC's pulsed spallation neutron source, a cryogenic hydrogen system has been operated to provide liquid para-hydrogen (20K and 1.5 MPa) to the moderators since 2008. Typical operating period of the cryogenic hydrogen system was approximately 3 months continuously. However, the pressure differences between No.1, No.2 heat exchangers (HXs) and an adsorber (ADS) in the helium refrigerator had begun to increase rapidly since the beginning of 2015, the refrigerator could not be operated continuously. The impurity in the refrigerator was measured by newly introduced quadrat mass spectrometer, but no significant impurities was observed. We suspected the oil contamination from the helium compressor, as it caused performance degradation of the cryogenic system in other facilities, such as RIKEN, CERN, etc. In the summer outage in 2016, we cleaned the HXs with Freon to remove the oil contamination, and replaced the activate charcoals of ADS and oil separator (OS-5). As a result, the performance of the helium refrigerator was recovered completely.


Present fabrication status of spare moderators and reflector in J-PARC spallation neutron source

勅使河原 誠; 原田 正英; 大井 元貴; 高田 弘

Journal of Physics; Conference Series, 1021(1), p.012061_1 - 012061_4, 2018/06

大強度陽子加速器施設(J-PARC)の物質・生命科学実験施設(MLF)では、高エネルギーパルス陽子ビーム(3GeV, 25Hz)を用いた核破砕反応により発生した中性子を、液体水素モデレータで減速し、実験装置にパルス冷熱中性子を供給する。モデレータや反射体容器構造材の放射線損傷により2020年ごろに交換時期を迎える。現在、交換に向けて、モデレータ及び反射体の予備機製作を進めている。予備機は、現在MLFで使用しているものと外観上は同じであるが、内部構造において、大きく2つ改良を加えた。一つは、水素輸送配管に線膨張係数の最も小さなインバー材を採用したこと。もう一つは、中性子ビームパルスをシャープにする熱中性子吸収材として、新たに金・インジウム・カドミウム(Au-In-Cd)材を開発したことである。5重の多重配管を構成する水素輸送配管では、インバー材を採用することで、熱収縮量を確保するために必要であった偏心構造を同軸構造に変え、製作性を大きく向上させた。熱中性子吸収材として、Au-In-Cd材は、残留放射能を大きく軽減する材料で、この用途に初めて開発されたものである。本件では、これら材料を導入したモデレータ・反射体の製作状況について報告する。


Recent issues encountered by AMATERAS; A Cold-neutron disk-chopper spectrometer

中島 健次; 河村 聖子; 菊地 龍弥*; 古府 麻衣子; 川北 至信; 稲村 泰弘; 神原 理*; 青山 和弘*; 若井 大介*; 原田 正英; et al.

Journal of Physics; Conference Series, 1021(1), p.012031_1 - 012031_5, 2018/06

We report recent issues that have been encountered by AMATERAS, which is a cold-neutron disk-chopper spectrometer installed at the Materials and Life Science Experimental Facility at J-PARC. After the last ICANS meeting held in 2014, AMATERAS has continued its user program. On the other hand, the spectrometer has faced several problems, such as a weak shield at the beam dump, failure of one of the chopper disks and many such problems, which we are currently investigating. Further, several instrumental improvements have been performed, such as background reduction, fixing badly designed parts and other such improvements. Our extensive experience obtained in the period of more than 7 years on one of the world's first pulse-shaping chopper spectrometers may help other researchers who are operating or planning to construct similar spectrometers.


Magnetic-ordering propagation vectors of terbium hexaboride revisited

岩佐 和晃*; 伊賀 文俊*; 茂吉 武人*; 中尾 朗子*; 大原 高志

Journal of the Physical Society of Japan, 87(6), p.064705_1 - 064705_5, 2018/06

The magnetic-ordered state of a single-crystal sample of TbB$$_{6}$$ has been studied with the high-precision neutron diffraction instrument SENJU installed at BL18 of the Materials and Life Science Facility in J-PARC. We observed new Bragg-reflection spots characterized by a propagation vector $$q_{rm M2}$$ = (1/4, 1/4, 0) below the N$'e$el temperature $$T_{rm N}$$ $$approx$$ 20 K, in addition to the $$q_{rm M1}$$ = (1/4, 1/4. 1/2) reported in the previous literatures. Because X-ray Thomson scattering measurements do not detect the $$q_{rm M2}$$ superlattice reflections at 13 K, $$q_{rm M2}$$ is a new magnetic-ordering propagation vector. The magnetic multi-q structure of TbB$$_{6}$$ is similar to that of CeB$$_{6}$$, whereas the ratio of the $$q_{rm M2}$$ amplitude to that of qM1 is smaller than in CeB$$_{6}$$. The combination of $$q_{rm M1}$$ and $$q_{rm M2}$$ is expected to assist the $$q_{rm L1}$$ = (1/2, 0, 0) lattice modulation.


Pressure-induced stacking disorder in boehmite

石井 優佑*; 小松 一生*; 中野 智志*; 町田 真一*; 服部 高典; 佐野 亜沙美; 鍵 裕之*

Physical Chemistry Chemical Physics, 20(24), p.16650 - 16656, 2018/06



Effect of electron correlations on spin excitation bandwidth in Ba$$_{0.75}$$K$$_{0.25}$$Fe$$_{2}$$As$$_{2}$$ as seen via time-of-flight inelastic neutron scattering

村井 直樹; 鈴木 雄大*; 出田 真一郎*; 中島 正道*; 田中 清尚*; 池田 浩章*; 梶本 亮一

Physical Review B, 97(24), p.241112_1 - 241112_6, 2018/06



Odd and even modes of neutron spin resonance in the bilayer iron-based superconductor CaKFe$$_{4}$$As$$_{4}$$

Xie, T.*; Wei, Y.*; Gong, D.*; Fennell, T.*; Stuhr, U.*; 梶本 亮一; 池内 和彦*; Li, S.*; Hu, J.*; Luo, H.*

Physical Review Letters, 120(26), p.267003_1 - 267003_7, 2018/06

We report an inelastic neutron scattering study on the spin resonance in the bilayer iron-based superconductor CaKFe$$_4$$As$$_4$$. In contrast to its quasi-two-dimensional electron structure, three strongly $$L$$-dependent modes of spin resonance are found below $$T_c$$ = 35 K. The mode energies are below and linearly scale with the total superconducting gaps summed on the nesting hole and electron pockets, essentially in agreement with the results in cuprate and heavy fermion superconductors. This observation supports the sign-reversed Cooper-pairing mechanism under multiple pairing channels and resolves the long-standing puzzles concerning the broadening and dispersive spin resonance peak in iron pnictides. More importantly, the triple resonant modes can be classified into odd and even symmetries with respect to the distance of Fe-Fe planes within the Fe-As bilayer unit. Thus, our results closely resemble those in the bilayer cuprates with nondegenerate spin excitations, suggesting that these two high-$$T_c$$ superconducting families share a common nature.



村松 壽晴

レーザ加工学会誌, 25(2), p.81 - 85, 2018/06



Elastic and dynamical structural properties of La and Mn-doped SrTiO$$_{3}$$ studied by neutron scattering and their relation with thermal conductivities

梶本 亮一; 中村 充孝; 村井 直樹; 社本 真一; 本田 孝志*; 池田 一貴*; 大友 季哉*; 畑 博人*; 江藤 貴弘*; 野田 正亮*; et al.

Scientific Reports (Internet), 8(1), p.9651_1 - 9651_8, 2018/06

The electron-doped SrTiO$$_{3}$$ exhibits good thermoelectric properties, which makes this material a promising candidate of an n-type oxide thermoelectric device. Recent studies indicated that only a few percent co-doping of La and Mn in SrTiO$$_{3}$$ substantially reduces the thermal conductivity, thereby greatly improving the thermoelectric figure of merit at room temperature. Our time-of-flight neutron scattering studies revealed that by doping both La and Mn into SrTiO$$_{3}$$, the inelastic scattering spectrum shows a momentum-independent increase in the low-energy spectral weight approximately below 10 meV. The increase in the low-energy spectral weight exhibits a clear correlation with thermal conductivity. The correlation is attributed to dynamical and local structural fluctuations caused by the Jahn-Teller instability in Mn$$^{3+}$$ ions coupled with the incipient ferroelectric nature of SrTiO$$_{3}$$, as the origin of the low thermal conductivity.


Instrumental resolution of the chopper spectrometer 4SEASONS evaluated by Monte Carlo simulation

梶本 亮一; 佐藤 研太朗*; 稲村 泰弘; 藤田 全基*

AIP Conference Proceedings 1969, p.050004_1 - 050004_8, 2018/05

We performed simulations of the resolution function of the 4SEASONS spectrometer at J-PARC by using the Monte Carlo simulation package McStas. The simulations showed reasonably good agreement with analytical calculations of energy and momentum resolutions by using a simplified description. We implemented new functionalities in Utsusemi, the standard data analysis tool used in 4SEASONS, to enable visualization of the simulated resolution function and predict its shape for specific experimental configurations.


High-pressure-high-temperature study of benzene; Refined crystal structure and new phase diagram up to 8 GPa and 923 K

Chanyshev, A. D.*; Litasov, K. D.*; Rashchenko, S.*; 佐野 亜沙美; 鍵 裕之*; 服部 高典; Shatskiy, A. F.*; Dymshits, A. M.*; Sharygin, I. S.*; 肥後 祐司*

Crystal Growth & Design, 18(5), p.3016 - 3026, 2018/05





大澤 崇人; 福岡 孝昭*

月刊地球, 40(5), p.302 - 309, 2018/05


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